Evonik

Dynasylan 40

Ethyl polysilicate

Dynasylan 40 is a colorless, low-viscosity liquid with an SiO2 content of 40%. The polysilicic acids still have a sufficient content of ethoxy groups which can be activated by acid- or base-catalyzed hydrolysis. Condensation starts even during hydrolysis, with the formation of relatively large polymeric molecules. During storage of these hydrolysates, condensation continues until a gel is formed, where the rate depends on the degree of hydrolysis.

The action of the hydrolysates as binders is based on the continuation of the hydrolysis with subsequent gelation and dehydration to give polymeric SiO2 structures.

Key Features

Dynasylan 40 is immiscible with water, so hydrolysis therefore requires a cosolvent as solubilizer.

Dynasylan 40 is formed in the presence of water from tetraethyl silicate (Si[OEt]4) by partial hydrolysis of the ethoxy groups to hydroxyl groups and subsequent condensation with formation of siloxane bonds (-Si-O-Si-).

Dynasylan 40 is also used as starting material for sol-gel processes.

Recommended Applications

Dynasylan® 40 is used to deposit silicic acid formed as a result of complete hydrolysis. The resulting silicic acid bonds well to many inorganic substrates, such as glass, ceramic, metal, fillers, pigments and synthetic fibers. The deposition of a thin SiO2 layer improves the chemical and thermal stability and mechanical properties.

 

Other applications are:

  • Crosslinker component in cold-curing silicone rubber systems
  • Binder, especially as a Dynasylan 40 hydrolysates for molds used e.g. in the precision foundry industry.
  • Hardening component in dentistry for impression materials and as binder for embedding material